(2S,2'S,3S,3'S)-BIBOP

Name: (2S,2'S,3S,3'S)-BIBOP
Brand: ChemScene
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CAS No. 1202033-17-7
Cat. No. CS-0088369
Purity≥98%
MDL No.MFCD31707603

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 1202033-17-7

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General Information

CAS No. 1202033-17-7
Cat. No. CS-0088369
Purity ≥98%
MDL No. MFCD31707603
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₂₂H₂₈O₂P₂
Molecular Weight 386.40
Synonym(s) None
SMILES [H][C@@]1([P@](C(C)(C)C)C(C=CC=C2)=C2O1)[C@]3([H])[P@@](C(C)(C)C)C4=CC=CC=C4O3

Description

(2S,2'S,3S,3'S)-BIBOP is a chiral bisphosphine ligand featuring rigid, stereodefined architecture that enhances enantioselectivity in transition metal catalysis. This bench-stable, moisture-tolerant ligand integrates seamlessly into palladium- and nickel-catalyzed cross-coupling reactions, delivering high stereocontrol with minimal catalyst loading under standard conditions.

Application

(2S,2'S,3S,3'S)-BIBOP serves as a chiral bisphosphine ligand enabling highly enantioselective transition-metal-catalyzed reactions, particularly in palladium- and nickel-catalyzed cross-couplings. Its rigid, well-defined stereochemistry facilitates precise control over asymmetric induction, while its bench-stable nature and compatibility with diverse functional groups support reliable application in complex molecule synthesis.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

TPSA 18.46
LogP 5.6352
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 1

Key Words

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(2S,2'S,3S,3'S)-BIBOP

CAS No. 1202033-17-7

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