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CS-W001157 4
Total: USD 88.00

1-Methyl-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]Heptane

  • CAS No. 1195-92-2

  • Cat. No. CS-0442167
  • Purity≥98%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

1-Methyl-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]Heptane|CS-0442167

Structure of 1195-92-2

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General Information

  • CAS No. 1195-92-2
  • Cat. No. CS-0442167
  • Purity ≥98%
  • MDL No. None
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₁₆O
  • Molecular Weight 152.23
  • Synonym(s) p-Menth-8-ene, 1,2-epoxy-
  • SMILES C=C(C)C1CCC2(C)C(C1)O2

Description

This bicyclic ether features a strategically positioned exocyclic double bond and a methyl-substituted aromatic-like ring system, delivering enhanced stability and reactivity in Diels-Alder transformations. The 7-oxabridge imparts polarity and directional control, enabling selective cycloadditions under mild conditions.

Synthesis

  • Route1
    • null|null
      138-86-3
    • ~93%
    • In-stock
      1-Methyl-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]Heptane|CS-0442167
      1195-92-2

    References

    • Ravikumar; Barbier, Francis; Begue, Jean-Pierre; Bonnet-Delpon, Daniele Tetrahedron, 1998 , vol. 54, # 26 p. 7457 - 7464
  • Route2
    • null|null
      138-86-3
    • ~%
    • In-stock
      1-Methyl-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]Heptane|CS-0442167
      1195-92-2
    • In-stock
      Carvone|CS-0033814
      99-49-0
    • Carveol, ≥95%|CS-1269153
      99-48-9

    References

    • Anastasiadis, Nikolaos C.; Bilis, George; Plakatouras, John C.; Raptopoulou, Catherine P.; Psycharis, Vassilis; Beavers, Christine; Teat, Simon J.; Louloudi, Maria; Perlepes, Spyros P. Polyhedron, 2013 , vol. 64, p. 189 - 202
  • Route3
    • null|null
      138-86-3
    • ~86%
    • null|null
      96-08-2
    • In-stock
      1-Methyl-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]Heptane|CS-0442167
      1195-92-2

    References

    • Amarante, Tatiana R.; Neves, Patricia; Valente, Anabela A.; Almeida Paz, Filipe A.; Fitch, Andrew N.; Pillinger, Martyn; Goncalves, Isabel S. Inorganic Chemistry, 2013 , vol. 52, # 8 p. 4618 - 4628

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H227-H302
Precautionary Statements : P210-P264-P270-P280-P330-P370+P378-P403-P501

Quality Control

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Computational Chemistry Data

  • TPSA   12.53
  • LogP   2.5201
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   1

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