6-Bromo-2-methyloxazolo[5,4-b]pyridine

Name: 6-Bromo-2-methyloxazolo[5,4-b]pyridine
Brand: ChemScene
Availability: InStock
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CAS No. 116081-18-6
Cat. No. CS-0042137
Purity≥97%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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6-Bromo-2-methyloxazolo[5,4-b]pyridine|CS-0042137

Structure of 116081-18-6

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General Information

CAS No. 116081-18-6
Cat. No. CS-0042137
Purity ≥97%
MDL No. None
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₅BrN₂O
Molecular Weight 213.03
Synonym(s) 6-BROMO-2-METHYL-OXAZOLO[5,4-B]PYRIDINE
SMILES CC1=NC2=CC(Br)=CN=C2O1

Description

6-Bromo-2-methyloxazolo[5,4-b]pyridine features a fused oxazolo-pyridine core with a bromo substituent at the 6-position and a methyl group at the 2-position. This electron-deficient heterocycle serves as a pivotal scaffold for constructing complex nitrogen-containing architectures in medicinal chemistry and materials science.

Application

6-Bromo-2-methyloxazolo[5,4-b]pyridine serves as a versatile heterocyclic building block for medicinal chemistry and materials science applications. Its bromine substituent enables palladium-catalyzed cross-coupling reactions, while the oxazolopyridine core provides structural rigidity and favorable electronic properties. The methyl group enhances solubility and metabolic stability, facilitating downstream functionalization in drug discovery workflows. This compound exhibits excellent bench stability and is readily purified by standard chromatographic methods.

Synthesis

Route1
- 108-24-7
- ~%
- In-stock
  
  116081-18-6
References
- Takahashi; Koshiro Chemical and Pharmaceutical Bulletin, 1959 , vol. 7, p. 720,724
Route2
- 102170-55-8
- ~%
- In-stock
  
  116081-18-6
References
- Takahashi; Koshiro Chemical and Pharmaceutical Bulletin, 1959 , vol. 7, p. 720,724

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 38.92
LogP 2.29372
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Building Blocks Skeleton Aromatic heterocycle compounds Oxazole compounds

Key Words

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6-Bromo-2-methyloxazolo[5,4-b]pyridine

CAS No. 116081-18-6

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