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(E)-tert-Butyldimethyl((3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)oxy)silane

  • CAS No. 114653-19-9

  • Cat. No. CS-0154945
  • Purity≥95%
  • MDL No.MFCD15144803

*For research and further manufacturing use only, not for direct human use.

(E)-tert-Butyldimethyl((3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)oxy)silane|CS-0154945

Structure of 114653-19-9

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General Information

  • CAS No. 114653-19-9
  • Cat. No. CS-0154945
  • Purity ≥95%
  • MDL No. MFCD15144803
  • Storage 4°C, sealed storage, away from moisture
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₅H₃₁BO₃Si
  • Molecular Weight 298.31
  • Synonym(s) None
  • SMILES C(=C/CO[Si](C(C)(C)C)(C)C)\B1OC(C)(C)C(C)(C)O1

Synthesis

  • Route1
    • In-stock
      tert-Butyldimethyl(prop-2-ynyloxy)silane|CS-M1108
      76782-82-6
    • null|null
      25015-63-8
    • ~95%
    • In-stock
      (E)-tert-Butyldimethyl((3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)oxy)silane|CS-0154945
      114653-19-9

    References

    • Tanaka, Kazuo; Ohashi, Wataru; Okada, Hiroshi; Chujo, Yoshiki Tetrahedron Letters, 2014 , vol. 55, # 9 p. 1635 - 1639
  • Route2

    References

    • Takahashi, Kou; Ishiyama, Tatsuo; Miyaura, Norio Journal of Organometallic Chemistry, 2001 , vol. 625, # 1 p. 47 - 53
  • Route3
    • null|null
      18162-48-6
    • ~%
    • In-stock
      (E)-tert-Butyldimethyl((3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)oxy)silane|CS-0154945
      114653-19-9

    References

    • MERCK SHARP and DOHME CORP.; COX, Christopher, D.; DUDKIN, Vadim; KERN, Jeffrey; LAYTON, Mark, E.; RAHEEM, Izzat, T. Patent: WO2013/28590 A1, 2013 ; WO 2013/028590 A1

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H312-H332
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P501

Quality Control

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Computational Chemistry Data

  • TPSA   27.69
  • LogP   4.1958
  • H_Acceptors   3
  • H_Donors   0
  • Rotatable_Bonds   4

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