Tetrapropylammonium perruthenate

Name: Tetrapropylammonium perruthenate
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CAS No. 114615-82-6
Cat. No. CS-W007801
Purity≥98%
MDL No.MFCD00074914

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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Tetrapropylammonium perruthenate|CS-W007801

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General Information

CAS No. 114615-82-6
Cat. No. CS-W007801
Purity ≥98%
MDL No. MFCD00074914
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₂₈NO₄Ru
Molecular Weight 351.43
Synonym(s) TPAP
SMILES CCC[N+](CCC)(CCC)CCC.O=[Ru](=O)([O-])=O

Description

Tetrapropylammonium perruthenate is a mild oxidizing agent used for the oxidation of alcohols to corresponding carbonyl compounds. It is a non-volatile, air-stable, and readily soluble reagent, which can be used either stoichiometrically or catalytically with a suitable co-oxidant.Tetrapropylammonium perruthenate (TPAP) can be used as a catalyst: For the conversion of sulfides to sulfones by oxidation reaction. In the isomerization of allylic alcohols into the corresponding saturated carbonyl derivatives.Along with N-methylmorpholine N-oxide (NMO) for the cleavage of glycol to carboxylic acids.TPAP can also be used as an oxidizing reagent:For the oxidation of benzyl alcohol to benzaldehyde and steroidal alcohols to corresponding ketones.To convert N,N-dihydroxyimidazolidines to nitronyl nitroxide free radicals. To oxidize hydroxyl-substituted tri-n-butylammonium trifluoroborates to aldehydes and ketones without concomitant cleavage of the carbon-boron bond.

Safety Information

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GHS Pictogram :	GHS No : GHS03
Signal Word : Danger	UN#: 1479
Class : 5.1	Packing Group : Ⅱ
Hazard Statements : H272-H315-H319-H335
Precautionary Statements : P210-P220-P280-P370+P378-P501

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Computational Chemistry Data

TPSA 74.27
LogP 1.8953
H_Acceptors 4
H_Donors 0
Rotatable_Bonds 8

Other Classifications

Bioactive Molecules Dye and Bio-assay Reagents

General Reagents Oxidants Other Oxidant

Life Science Biochemicals Detergents

Catalysts and Ligands Catalysts Transition Metal Catalysts Ru Catalysts

Catalysis C-H Activation Ruthenium Compounds

Catalysis Oxidation Metal Catalysts for Oxidation

Catalysis Transition Elements Ruthenium

Chemical Synthesis Synthetic Reagents Oxidation Oxidants (Other)

Catalysis Compounds by Element Classes Metal Compounds Transition Metal Compounds

Catalysis Asymmetric Synthesis Chiral Catalysts, Chiral Ligands, Chiral Reagents Chiral Catalysts (Other)

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Tetrapropylammonium perruthenate

CAS No. 114615-82-6

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