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CS-W001157 4
Total: USD 88.00

Dipivaloylmethane

  • CAS No. 1118-71-4

  • Cat. No. CS-W008804
  • Purity≥95%
  • MDL No.MFCD00008848

*For research and further manufacturing use only, not for direct human use.

Dipivaloylmethane|CS-W008804

Structure of 1118-71-4

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General Information

  • CAS No. 1118-71-4
  • Cat. No. CS-W008804
  • Purity ≥95%
  • MDL No. MFCD00008848
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₁H₂₀O₂
  • Molecular Weight 184.28
  • Synonym(s) None
  • SMILES CC(C)(C)C(CC(C(C)(C)C)=O)=O

Description

2,2,6,6-Tetramethyl-3,5-heptanedione is a bidentate ligand used in the synthesis of stable complexes with lanthanide ions. 2,2,6,6-Tetramethyl-3,5-heptanedioneis a stable, anhydrous reagent. It undergoes O-additions and C-additions. In various reactions, it acts as an air-stable ligand for metal catalysts. Furthermore, it serves as a substrate for heterocycles.2,2,6,6-tetramethyl-3,5-heptanedione was used in the synthesis of -aryl--diketones and dicyanamidobenzene-bridge diruthenium complex.2,2,6,6-Tetramethyl-3,5-heptanedione used as a ancillary ligand in the synthesis of orange-emitting iridium(III) complex.

Synthesis

  • Route1
    • null|null
      75-97-8
    • null|null
      598-98-1
    • ~63%
    • In-stock
      Dipivaloylmethane|CS-W008804
      1118-71-4

    References

    • Nandurkar, Nitin S.; Bhanushali, Mayur J.; Patil, Dinkar S.; Bhanage, Bhalchandra M. Synthetic Communications, 2007 , vol. 37, # 23 p. 4111 - 4115
  • Route2
    • null|null
      3282-30-2
    • ~%
    • In-stock
      Dipivaloylmethane|CS-W008804
      1118-71-4

    References

    • Journal of the American Chemical Society, , vol. 73, p. 901
  • Route3
    • null|null
      75-97-8
    • Phenyl pivalate|CS-1014291
      4920-92-7
    • ~%
    • In-stock
      Dipivaloylmethane|CS-W008804
      1118-71-4

    References

    • Journal of the American Chemical Society, , vol. 73, p. 901

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   34.14
  • LogP   2.6069
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   2

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