4-Bromo-2-methylpyrimidine

Name: 4-Bromo-2-methylpyrimidine
Brand: ChemScene
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CAS No. 1114560-76-7
Cat. No. CS-W006607
Purity≥95%
MDL No.MFCD11223245

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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General Information

CAS No. 1114560-76-7
Cat. No. CS-W006607
Purity ≥95%
MDL No. MFCD11223245
Storage -20°C, sealed storage, away from moisture
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₅H₅BrN₂
Molecular Weight 173.01
Synonym(s) 4-bromo-2-methyl-pyrimidine
SMILES BrC1=NC(=NC=C1)C

Description

4-Bromo-2-methylpyrimidine serves as a key heterocyclic scaffold in medicinal chemistry, offering a reactive bromine handle for cross-coupling and a methyl group enabling strategic electronic modulation. This bench-stable building block facilitates efficient access to diverse pyrimidine-based architectures through palladium-catalyzed transformations and nucleophilic substitutions.

Application

4-Bromo-2-methylpyrimidine serves as a versatile building block in medicinal chemistry, enabling palladium-catalyzed cross-coupling reactions for the construction of biaryl and heteroaryl scaffolds. The bromine atom facilitates efficient functionalization under standard Suzuki, Stille, or Negishi conditions, while the methyl group enhances solubility and modulates electronic properties. Bench-stable and readily purified by recrystallization, it functions reliably in multi-step syntheses of kinase inhibitors and other pharmaceutical intermediates.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 25.78
LogP 1.54752
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Building Blocks Skeleton Aromatic heterocycle compounds Pyrimidine compounds

Key Words

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4-Bromo-2-methylpyrimidine

CAS No. 1114560-76-7

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