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CS-W001157 4
Total: USD 88.00

Methyl undec-10-enoate

  • CAS No. 111-81-9

  • Cat. No. CS-0068709
  • Purity97% (stabilized with MEHQ)
  • MDL No.MFCD00016689

*For research and further manufacturing use only, not for direct human use.

Methyl undec-10-enoate|CS-0068709

Structure of 111-81-9

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General Information

  • CAS No. 111-81-9
  • Cat. No. CS-0068709
  • Purity 97% (stabilized with MEHQ)
  • MDL No. MFCD00016689
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₂H₂₂O₂
  • Molecular Weight 198.30
  • Synonym(s) Methyl-10-undecenoate
  • SMILES C=CCCCCCCCCC(OC)=O

Description

Methyl 10-undecenoate is the chain stopper in the polymerization of long-chain aliphatic ,-diene through acyclic diene metathesis (ADMET). This helps in tuning the molecular weight of the resulting polyester in a range varying from 10 to 45 kDa.Methyl 10-undecenoate is an unsaturated fatty acid ester that can be used as a substrate: To prepare bifunctional polymer precursors via hydroformylation reaction. To synthesize ,-ester amides via aminocarbonylation in the presence of palladium catalyst. To modify commercial silicone monomer, 1,3,5,7-tetramethylcyclotetrasiloxane, for the preparation of silicone hollow nano/microstructures in water by hydrosilylation reaction.

Synthesis

  • Route1
    • null|null
      67-56-1
    • In-stock
      10-Undecenoic acid,98% stabilized with TBC|CS-4383
      112-38-9
    • ~98%
    • In-stock
      Methyl undec-10-enoate|CS-0068709
      111-81-9

    References

    • Giri; Prabhavathi Devi; Gangadhar; Narasimha Rao; Lingaiah; Sai Prasad; Prasad Synthetic Communications, 2006 , vol. 36, # 1 p. 7 - 11
  • Route2
    • null|null
      251922-69-7
    • null|null
      74-88-4
    • ~93%
    • In-stock
      Methyl undec-10-enoate|CS-0068709
      111-81-9

    References

    • Boutros, Andre; Legros, Jean-Yves; Fiaud, Jean-Claude Tetrahedron, 2000 , vol. 56, # 15 p. 2239 - 2246
  • Route3
    • In-stock
      Methyl oleate|CS-0022975
      112-62-9
    • null|null
      54509-73-8
    • ~%
    • In-stock
      Methyl undec-10-enoate|CS-0068709
      111-81-9

    References

    • US2013/5937 A1, ; Page/Page column 23 ;

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07,GHS09
Signal Word : Warning
UN#: 3082
Class : 9
Packing Group : Ⅲ
Hazard Statements : H302+H332-H410
Precautionary Statements : P261-P264-P270-P271-P273-P304+P340-P330-P391-P501

Quality Control

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Computational Chemistry Data

  • TPSA   26.3
  • LogP   3.4662
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   9

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