2-Chloro-4-fluorobromobenzene

Name: 2-Chloro-4-fluorobromobenzene
Brand: ChemScene
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CAS No. 110407-59-5
Cat. No. CS-W002418
Purity≥98%
MDL No.MFCD00142587

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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2-Chloro-4-fluorobromobenzene|CS-W002418

Structure of 110407-59-5

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General Information

CAS No. 110407-59-5
Cat. No. CS-W002418
Purity ≥98%
MDL No. MFCD00142587
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₃BrClF
Molecular Weight 209.44
Synonym(s) 4-Bromo-3-chlorofluorobenzene
SMILES BrC1=C(Cl)C=C(F)C=C1

Description

2-Chloro-4-fluorobromobenzene is a halogenated aromatic compound featuring complementary reactive sites for cross-coupling and functionalization. The ortho-chloro and para-fluoro substituents enable sequential transformations, while the bromine moiety serves as a robust handle for palladium-catalyzed coupling reactions under standard conditions. This molecule combines high stability with predictable reactivity, making it a reliable intermediate in synthetic sequences requiring precise regiocontrol.

Application

2-Chloro-4-fluorobromobenzene serves as a versatile building block in cross-coupling chemistry, enabling the construction of biaryl scaffolds via palladium-catalyzed reactions. Its orthogonal halogenation pattern facilitates sequential functionalization, while the bromine center offers high reactivity under standard Suzuki, Stille, and Negishi conditions. Bench-stable and amenable to purification by distillation or column chromatography, it supports efficient synthesis of complex aromatic architectures relevant to pharmaceutical and agrochemical research.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 0
LogP 3.2416
H_Acceptors 0
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Chloro-4-fluorobromobenzene

CAS No. 110407-59-5

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