Lot numbers can be found on the outside label of a product:
9,9-Dimethylfluoren-2-amine
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CAS No. 108714-73-4
- Cat. No. CS-0030562
- Purity≥97%
- MDL No.MFCD09953790
*For research and further manufacturing use only, not for direct human use.
Structure of 108714-73-4
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General Information
- CAS No. 108714-73-4
- Cat. No. CS-0030562
- Purity ≥97%
- MDL No. MFCD09953790
- Storage 4°C, protect from light
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₁₅H₁₅N
- Molecular Weight None
- Synonym(s) 2-Amino-9,9-dimethylfluorene
- SMILES NC1=CC(C(C)(C)C2=C3C=CC=C2)=C3C=C1
Description
9,9-Dimethylfluoren-2-amine features a sterically hindered fluorene core with a primary amine at the 2-position, enabling robust coupling reactions. The dimethyl substitution enhances stability and solubility in organic media, while the electron-rich aromatic system facilitates efficient participation in transition-metal-catalyzed transformations. This scaffold serves as a versatile building block for functionalized materials and bioactive molecules.
Application
9,9-Dimethylfluoren-2-amine serves as a robust scaffold for constructing biaryl and heterocyclic architectures, leveraging its sterically hindered amine functionality. The dimethyl-substituted fluorene core imparts enhanced thermal stability and facilitates purification via flash chromatography. It functions effectively in Suzuki-Miyaura coupling reactions and acts as a versatile building block in the synthesis of functionalized ligands and advanced materials.
Synthesis
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Route1
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In-stock
28320-31-2 - ~%
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In-stock
108714-73-4
References
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WO2012/15265 A1, ; Page/Page column 15 ;
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Route2
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In-stock
605644-46-0 - ~89%
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In-stock
108714-73-4
References
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Zhang, Hua; Fan, Jiangli; Dong, Huijuan; Zhang, Shuangzhe; Xu, Wenyou; Wang, Jingyun; Gao, Pan; Peng, Xiaojun Journal of Materials Chemistry B, 2013 , vol. 1, # 40 p. 5450 - 5455
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Route3
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63021-04-5 - ~%
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In-stock
108714-73-4
References
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EP2468725 A1, ; Page/Page column 121 ;
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 26.02
- LogP 3.5751
- H_Acceptors 1
- H_Donors 1
- Rotatable_Bonds 0
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Key Words
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