6-Bromo-1-methyl-1H-pyrrolo[3,2-b]pyridine

Name: 6-Bromo-1-methyl-1H-pyrrolo[3,2-b]pyridine
Brand: ChemScene
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CAS No. 1086064-46-1
Cat. No. CS-0043070
Purity≥97%
MDL No.MFCD23703531

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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6-Bromo-1-methyl-1H-pyrrolo[3,2-b]pyridine|CS-0043070

Structure of 1086064-46-1

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General Information

CAS No. 1086064-46-1
Cat. No. CS-0043070
Purity ≥97%
MDL No. MFCD23703531
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₇BrN₂
Molecular Weight 211.06
Synonym(s) 6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine6-broMo-1-Methyl-1H-pyrrolo[3,2-b]pyridine
SMILES CN1C=CC2=NC=C(Br)C=C21

Description

6-Bromo-1-methyl-1H-pyrrolo[3,2-b]pyridine is a heteroaromatic building block featuring a brominated pyrrolopyridine core with a methyl group at the nitrogen. This electron-deficient scaffold enables direct functionalization in cross-coupling reactions, integrating efficiently into complex molecular architectures under standard conditions.

Application

6-Bromo-1-methyl-1H-pyrrolo[3,2-b]pyridine serves as a versatile building block for the synthesis of biologically active heterocycles. Its bromine substituent enables palladium-catalyzed cross-coupling reactions, while the methyl group enhances solubility and stability. The scaffold functions effectively in Suzuki, Stille, and Negishi couplings, facilitating efficient construction of complex pyrrolopyridine derivatives used in medicinal chemistry and agrochemical research.

Synthesis

Route1
- 1229457-88-8
- ~%
- In-stock
  
  1086064-46-1
References
- TAKEDA PHARMACEUTICAL COMPANY LIMITED; CHANG, Edcon; NOTZ, Wolfgang Reinhard Ludwig; WALLACE, Michael B. Patent: WO2014/11568 A1, 2014 ;

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 17.82
LogP 2.3358
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Building Blocks Skeleton Aromatic heterocycle compounds Pyrrole compounds

Key Words

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6-Bromo-1-methyl-1H-pyrrolo[3,2-b]pyridine

CAS No. 1086064-46-1

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