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CS-W001157 4
Total: USD 88.00

Diethyl allylphosphonate

  • CAS No. 1067-87-4

  • Cat. No. CS-0187363
  • Purity≥96%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

Diethyl allylphosphonate|CS-0187363

Structure of 1067-87-4

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General Information

  • CAS No. 1067-87-4
  • Cat. No. CS-0187363
  • Purity ≥96%
  • MDL No. None
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₇H₁₅O₃P
  • Molecular Weight 178.17
  • Synonym(s) diethyl prop-2-en-1-ylphosphonate
  • SMILES C=CCP(=O)(OCC)OCC

Application

Diethyl allylphosphonate serves as a versatile building block in synthetic organic chemistry, enabling efficient access to α,β-unsaturated phosphonates via Michael addition and Horner-Wadsworth-Emmons reactions. Its allylic functionality facilitates conjugate additions and cycloadditions, while the phosphonate group offers robust stability and ease of purification. The compound functions as a key reagent for constructing biologically relevant heterocycles and carbocyclic frameworks under mild conditions.

Synthesis

  • Route1
    • null|null
      106-95-6
    • null|null
      122-52-1
    • ~96%
    • In-stock
      Diethyl allylphosphonate|CS-0187363
      1067-87-4

    References

    • Tetrahedron, , vol. 66, # 3 p. 758 - 764
  • Route2
    • null|null
      106-95-6
    • null|null
      762-04-9
    • ~94%
    • In-stock
      Diethyl allylphosphonate|CS-0187363
      1067-87-4

    References

    • J. Gen. Chem. USSR (Engl. Transl.), , vol. 57, # 8 p. 1709 - 1711,1524 - 1525
  • Route3
    • null|null
      591-87-7
    • null|null
      762-04-9
    • ~82%
    • In-stock
      Diethyl allylphosphonate|CS-0187363
      1067-87-4

    References

    • Synthesis, , # 7 p. 563 - 564

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   35.53
  • LogP   2.4385
  • H_Acceptors   3
  • H_Donors   0
  • Rotatable_Bonds   6

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