2-(4-Bromophenyl)-1,3-dioxolane

Name: 2-(4-Bromophenyl)-1,3-dioxolane
Brand: ChemScene
Availability: InStock
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CAS No. 10602-01-4
Cat. No. CS-0035897
Purity≥96%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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2-(4-Bromophenyl)-1,3-dioxolane|CS-0035897

Structure of 10602-01-4

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Description

This 2-(4-bromophenyl)-1,3-dioxolane features a stable dioxolane ring fused to a para-brominated phenyl group, enabling reliable incorporation into cross-coupling and functionalization workflows. The bromine handle facilitates palladium-catalyzed transformations, while the cyclic acetal offers enhanced stability compared to open-chain analogs.

Application

2-(4-Bromophenyl)-1,3-dioxolane serves as a stable, bench-ready building block for Suzuki-Miyaura and other palladium-catalyzed cross-coupling reactions. The bromoaryl group enables efficient functionalization under standard conditions, while the 1,3-dioxolane ring enhances solubility and stability compared to free aldehydes. Its predictable reactivity and ease of purification make it a practical choice for constructing biaryl motifs in medicinal chemistry and materials synthesis.

General Information

CAS No. 10602-01-4
Cat. No. CS-0035897
Purity ≥96%
MDL No. None
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₉H₉BrO₂
Molecular Weight 229.07
Synonym(s) 4-Bromobenzaldehyde Ethylene Acetal
SMILES C1=C(C=CC(=C1)Br)C2OCCO2

Computational Chemistry Data

TPSA 18.46
LogP 2.4945
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 1

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Skeleton Aliphatic heterocycle compounds Dioxolane compounds

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-(4-Bromophenyl)-1,3-dioxolane

CAS No. 10602-01-4

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