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CS-W001157 4
Total: USD 88.00

Potassium trimethylsilanolate

  • CAS No. 10519-96-7

  • Cat. No. CS-0006201
  • Purity≥95%
  • MDL No.MFCD00013421

*For research and further manufacturing use only, not for direct human use.

Potassium trimethylsilanolate|CS-0006201

Structure of 10519-96-7

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General Information

  • CAS No. 10519-96-7
  • Cat. No. CS-0006201
  • Purity ≥95%
  • MDL No. MFCD00013421
  • Storage 4°C, sealed storage, away from moisture
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₃H₉KOSi
  • Molecular Weight 128.29
  • Synonym(s) Trimethylsiloxypotassium; Potassium trimethylsilanolate
  • SMILES [K].O[Si](C)(C)C

Description

Potassium trimethylsilanolate can be used as a reagent in the:Hydrolysis of nitriles to primary amides.Conversion of esters to carboxylic acids, and dialkyl phosphonates to their monoalkyl phosphonates.Synthesis of E-alkenes, and nitrocefin.It can also be used as a coupling promoter in cross-coupling reaction of aliphatic alkynylsilanols with aryl iodides.

Synthesis

  • Route1
    • null|null
      107-46-0
    • ~81%
    • In-stock
      Potassium trimethylsilanolate|CS-0006201
      10519-96-7

    References

    • Hyde, J. F.; Johannson, O. K.; Daudt, W. H.; Fleming, R. F.; Laudenslager, H. B.; Roche, M. P. Journal of the American Chemical Society, 1953 , vol. 75, p. 5615 - 5618 Full Text View citing articles Show Details Gmelin Handbook: Si: MVol.C, 84, page 231 - 233
  • Route2
    • null|null
      1450-14-2
    • ~86%
    • In-stock
      Potassium trimethylsilanolate|CS-0006201
      10519-96-7

    References

    • Koester, Roland; Seidel, Guenter; Wagner, Klaus; Wrackmeyer, Bernd Chemische Berichte, 1993 , vol. 126, # 2 p. 305 - 318
  • Route3

    References

    • Koester, Roland; Seidel, Guenter; Wagner, Klaus; Wrackmeyer, Bernd Chemische Berichte, 1993 , vol. 126, # 2 p. 305 - 318

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS05
Signal Word : Danger
UN#: 3263
Class : 8
Packing Group : Ⅱ
Hazard Statements : H314
Precautionary Statements : P260-P264-P280-P301+P330+P331-P304+P340-P363-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   20.23
  • LogP   0.1651
  • H_Acceptors   1
  • H_Donors   1
  • Rotatable_Bonds   0

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