4-Bromo-2-chloro-5-fluorophenol

Name: 4-Bromo-2-chloro-5-fluorophenol
Brand: ChemScene
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CAS No. 1036383-21-7
Cat. No. CS-0159320
Purity≥95%
MDL No.MFCD22414508

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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4-Bromo-2-chloro-5-fluorophenol|CS-0159320

Structure of 1036383-21-7

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General Information

CAS No. 1036383-21-7
Cat. No. CS-0159320
Purity ≥95%
MDL No. MFCD22414508
Storage RT, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₃BrClFO
Molecular Weight 225.44
Synonym(s) 4-BroMo-2-chloro-5-fluoro-phenol
SMILES OC1=CC(F)=C(Br)C=C1Cl

Description

4-Bromo-2-chloro-5-fluorophenol features a trifluorinated aromatic core with strategically positioned halogen substituents enabling precise downstream functionalization. This bench-stable phenolic scaffold integrates readily into complex molecular architectures, particularly in pharmaceutical intermediates and agrochemical development.

Application

4-Bromo-2-chloro-5-fluorophenol serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling efficient construction of substituted heterocycles via palladium-catalyzed cross-coupling reactions. Its ortho-halogenation pattern provides predictable regioselectivity in Suzuki-Miyaura and Stille couplings, while the phenolic hydroxyl group offers a handle for derivatization or protection. The compound exhibits good bench stability and is readily purified by crystallization, facilitating scalable applications in target-oriented synthesis.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 20.23
LogP 2.9472
H_Acceptors 1
H_Donors 1
Rotatable_Bonds 0

Other Classifications

Building Blocks Functional Group Fluoride

Building Blocks Functional Group Chloride

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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4-Bromo-2-chloro-5-fluorophenol

CAS No. 1036383-21-7

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