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(1R,4S)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2,3-dione

  • CAS No. 10334-26-6

  • Cat. No. CS-0179388
  • Molecule weight166.22
  • Purity≥98%
  • MDL No.MFCD24391444

*For research and further manufacturing use only, not for direct human use.

(1R,4S)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2,3-dione|CS-0179388

Structure of 10334-26-6

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General Information

  • CAS No. 10334-26-6
  • Cat. No. CS-0179388
  • Purity ≥98%
  • MDL No. MFCD24391444
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₁₄O₂
  • Molecular Weight 166.22
  • Synonym(s) Levogyration camphorquinone
  • SMILES C[C@@]12C(C)([C@H](CC2)C(C1=O)=O)C

Description

(1R)-()-Camphorquinone can be used as a chiral starting material for the preparation of: -Hydroxycamphors by selective reduction of keto groups using various vegetables. Camphor-1,2-diamine platinum(II) complexes for DNA interaction studies. Camphoric anhydride by unsensitized photo-oxidation in the presence of oxygen and polar solvents. Camphorquinone-based chiral homoallylic amine, which is reacted with aldehydes to produce homoallylic primary amines via imine formation followed by 2-azonia-Cope rearrangement.

Synthesis

  • Route1

    References

    • Kulhanek, Jiri; Bures, Filip; Simon, Petr; Bernd Schweizer Tetrahedron Asymmetry, 2008 , vol. 19, # 21 p. 2462 - 2469
  • Route2
    • null|null
      630095-62-4
    • ~82%
    • In-stock
      (1R,4S)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2,3-dione|CS-0179388
      10334-26-6

    References

    • Tan, Qitao; Wang, Yunying; Li, Daliang; Wen, Jiwu; You, Tianpa Synthesis, 2003 , # 12 p. 1869 - 1871
  • Route3

    References

    • Ohno, Atsuyoshi; Goto, Takehiko; Nakai, Jun-ichi; Oka, Shinzaburo Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 11 p. 3478 - 3481

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07,GHS08
Signal Word : Danger
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H334
Precautionary Statements : P261-P264-P270-P284-P304+P340-P330-P501

Quality Control

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Computational Chemistry Data

  • TPSA   34.14
  • LogP   1.5807
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   0

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