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CS-W001157 4
Total: USD 88.00

(1R,2S,4S)-2-(Chloromethoxy)-1-isopropyl-4-methylcyclohexane

  • CAS No. 103128-76-3

  • Cat. No. CS-0491957
  • Purity≥85%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

(1R,2S,4S)-2-(Chloromethoxy)-1-isopropyl-4-methylcyclohexane|CS-0491957

Structure of 103128-76-3

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General Information

  • CAS No. 103128-76-3
  • Cat. No. CS-0491957
  • Purity ≥85%
  • MDL No. None
  • Storage -20°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₁H₂₁ClO
  • Molecular Weight 204.74
  • Synonym(s) None
  • SMILES ClCO[C@@H]1[C@H](CC[C@H](C)C1)C(C)C

Description

(+)-Chloromethyl menthyl ether can be used:As a starting material for the synthesis of 1-methyl-3-(+)-methylmenthoxide imidazolium chloride, a key intermediate for the preparation of Ag(I) N-heterocyclic carbene, applicable as a catalyst in the diboration of alkenes.As a substrate in the synthesis of commercially important O-substituted -methoxymethylketones.To determine enantiomeric excess (ee) of an iron chiral auxiliary named [Fe(CO)(;5- C2H5)(PPh3)COCH3].

Synthesis

  • Route1
    • null|null
      110-88-3
    • In-stock
      (+)-Menthol|CS-W017993
      15356-60-2
    • ~87%
    • In-stock
      (1R,2S,4S)-2-(Chloromethoxy)-1-isopropyl-4-methylcyclohexane|CS-0491957
      103128-76-3

    References

    • Shatzmiller, Shimon; Dolithzky, Ben-Zion; Bahar, Eliezer Liebigs Annalen der Chemie, 1991 , # 4 p. 375 - 379

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   9.23
  • LogP   3.6601
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   3

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