6-Bromo-7-chloro-1H-benzo[d]imidazole

Name: 6-Bromo-7-chloro-1H-benzo[d]imidazole
Brand: ChemScene
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CAS No. 1008361-81-6
Cat. No. CS-0146717
Purity≥96%
MDL No.MFCD12828061

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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6-Bromo-7-chloro-1H-benzo[d]imidazole|CS-0146717

Structure of 1008361-81-6

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General Information

CAS No. 1008361-81-6
Cat. No. CS-0146717
Purity ≥96%
MDL No. MFCD12828061
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₄BrClN₂
Molecular Weight 231.48
Synonym(s) 5-bromo-4-chloro-1H-benzoimidazole
SMILES ClC1=C2C(N=CN2)=CC=C1Br

Description

6-Bromo-7-chloro-1H-benzo[d]imidazole features a fused bicyclic core with complementary halogen substituents at the 6 and 7 positions, enabling direct functionalization in cross-coupling reactions. The electron-deficient imidazole ring enhances reactivity in palladium-catalyzed transformations, while the bench-stable structure facilitates handling under standard conditions.

Application

6-Bromo-7-chloro-1H-benzo[d]imidazole serves as a versatile heterocyclic building block for medicinal chemistry and materials science. Its dual halogen substitution enables palladium-catalyzed cross-coupling reactions, facilitating the construction of biaryl and extended π-conjugated systems. The molecule exhibits excellent bench stability and compatibility with common protecting group strategies, enabling efficient functionalization in multistep syntheses.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H320-H335
Precautionary Statements : P261-P280-P302+P352

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Computational Chemistry Data

TPSA 28.68
LogP 2.9788
H_Acceptors 1
H_Donors 1
Rotatable_Bonds 0

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic heterocycle compounds Benzimidazole compounds

Key Words

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6-Bromo-7-chloro-1H-benzo[d]imidazole

CAS No. 1008361-81-6

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