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CS-W001157 4
Total: USD 88.00

1-Methyl-3-vinylbenzene,98% (stabilized with TBC)

  • CAS No. 100-80-1

  • Cat. No. CS-0110437
  • Purity96% (stabilized with TBC)
  • MDL No.MFCD00008617

*For research and further manufacturing use only, not for direct human use.

1-Methyl-3-vinylbenzene,98% (stabilized with TBC)|CS-0110437

Structure of 100-80-1

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General Information

  • CAS No. 100-80-1
  • Cat. No. CS-0110437
  • Purity 96% (stabilized with TBC)
  • MDL No. MFCD00008617
  • Storage -20°C, sealed storage, away from moisture
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₉H₁₀
  • Molecular Weight 118.18
  • Synonym(s) 3-Vinyltoluene (stabilized with TBC)
  • SMILES C=CC1=CC(C)=CC=C1

Description

1-Methyl-3-vinylbenzene, stabilized with TBC, features a vinyl group conjugated to an electron-rich aromatic ring, enabling efficient copolymerization. This bench-stable monomer integrates readily into styrenic and functional polymer systems, offering enhanced thermal resilience and controlled reactivity under standard conditions.

Application

1-Methyl-3-vinylbenzene (stabilized with TBC) serves as a versatile vinyl monomer for palladium-catalyzed cross-coupling reactions and Diels-Alder cycloadditions. Its ortho-substituted structure enhances regioselectivity in polymerization and heterocycle formation, while the stabilizing agent ensures bench stability and predictable reactivity. Functions effectively in synthetic routes requiring controlled alkene incorporation into complex scaffolds.

Synthesis

  • Route1
    • null|null
      54509-73-8
    • null|null
      591-17-3
    • ~84%
    • In-stock
      1-Methyl-3-vinylbenzene,98% (stabilized with TBC)|CS-0110437
      100-80-1

    References

    • Tetrahedron, , vol. 66, # 5 p. 1102 - 1110
  • Route2
    • null|null
      54509-73-8
    • In-stock
      1-Iodo-3-methylbenzene|CS-W014806
      625-95-6
    • ~71%
    • In-stock
      1-Methyl-3-vinylbenzene,98% (stabilized with TBC)|CS-0110437
      100-80-1

    References

    • ChemCatChem, , vol. 5, # 1 p. 159 - 172
  • Route3
    • null|null
      54509-73-8
    • null|null
      108-88-3
    • ~%
    • null|null
      622-97-9
    • In-stock
      1-Methyl-3-vinylbenzene,98% (stabilized with TBC)|CS-0110437
      100-80-1

    References

    • Journal of the American Chemical Society, , vol. 123, # 2 p. 337 - 338

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02,GHS07,GHS08
Signal Word : Danger
UN#: 2618
Class : 3
Packing Group : Ⅲ
Hazard Statements : H226-H304-H315-H319-H332-H335
Precautionary Statements : P210-P233-P240-P241-P242-P243-P261-P264-P271-P280-P302+P352-P304+P340-P331-P362+P364-P370+P378-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   2.63802
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   1

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